[期刊论文]


The first vitamin B6 zinc complex, pyridoxinato-zinc acetate: A 1D coordination polymer with polar packing through strong inter-chain hydrogen bonding

作   者:
Anne-Christine Chamayou;M.A. Neelakantan;S. Thalamuthu;Christoph Janiak;

出版年:2011

页     码:447 - 450
出版社:Elsevier BV


摘   要:

The biologically important pyridoxinato(1-) ligand (anionic vitamin B"6) shows the rare phenolate-hydroxymethyl chelation plus bridging mode through the pyridine-nitrogen atom towards zinc(II) to give the one-dimensional (1D) coordination polymer {(acetato-@kO)-aqua-@m-[2-methyl-3-oxy-4,5-di(hydroxymethyl)pyridine-@kN:O,O']zinc(II)}.monohydrate with polar packing of adjacent chains along the polar c axis (in space group Pc) through strong inter-chain hydrogen bonding.



关键字:

Zinc ; Vitamin B"6, pyridoxine ; Coordination polymer ; Polar packing


所属期刊
Inorganica Chimica Acta
ISSN: 0020-1693
来自:Elsevier BV