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Self-powered photodetectors (PDs) with distinguishable wavelength detection have great application potential in intelligent optoelectronics. However, slow response speed, low responsivity, and signal interference prevent its development and applications. Here, an asymmetric bipolar p-NiO/n-ZnO/p-Si heterojunction is designed as a wavelength-distinguishable PD by using two tandem p–n junctions to reduce the wavelength interference and effectively separate photo-generated carriers. Bidirectional transient photocurrents are achieved in the external circuit for ultraviolet and visible detection by smartly using the pyro-phototronic effect induced by the variations of spontaneous polarization and interface-induced polarization within the p–n–p junction. The transient peak-to-peak current are thus significantly improved by 2310% for 325 nm lasing and by 5950% for 442 nm lasing. This approach can be used to realize wavelength-distinguishable detection through flexibly selecting materials and using the pyro-phototronic effect. The designed PD might have potential applications in the fields of environmental detection, smart imaging, and intelligent optoelectronics.
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