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[期刊论文]
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Poly[[[μ3-3-(2-carboxylatophenyl)propionato][μ2- N , N ′-(ethane-1,2-diyl)bis(pyridine-4-carboxamide)]copper(II)] monohydrate], a layered coordination polymer with (4,4) topology
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作 者：
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Gabrielle J. Gaskin;Robert L. LaDuca;
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出版年：2023
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页 码：x230679 - x230679
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出版社：International Union of Crystallography (IUCr)
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摘 要：
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In the title compound, {[Cu(C 10 H 8 O 4 )(C 14 H 14 N 4 O 2 )]·H 2 O} n , the Cu II cations are coordinated in a square-pyramidal fashion, with trans pyridyl-N donor atoms from two N -(2-(pyridin-3-ylamino)ethyl)isonicotinamide (pein) ligands in the basal plane. The other three coordination sites are taken up by carboxylate O-atom donors from three different 3-(2-carboxyphenyl)propionate (cpp) ligands. The central ethylenediamine segments of the pein ligands are disordered equally over two sets of positions. {Cu 2 O 2 } rhomboid clusters are connected into [Cu(cpp)(pein)] n (4,4) coordination polymer grids by the full span of the cpp and pein ligands. Individual layer motifs stack in an AAA pattern along the a axis by means of interlayer hydrogen-bonding interactions.
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关键字：
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CRYSTAL STRUCTURE; COORDINATION POLYMER; LAYER; COPPER
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全文
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所属期刊
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ISSN:
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来自：International Union of Crystallography (IUCr)
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