|
[期刊论文]
|
Excess volumes and viscosities of mixtures of nitrobenzene and certain aromatic bases
|
作 者:
|
K. Govindan;G. Ravichandran;
|
|
出版年:1996
|
页 码:75 - 82
|
出版社:Springer Nature
|
摘 要:
|
Excess molar volumes V E , excess viscosities η E , excess Gibbs energy changes for viscous flow ΔG‡ E and interaction parameters d for binary mixtures of nitrobenzene with aniline, N-methylaniline and m-chloroaniline at selected compositions were determined from the measured values of densities and viscosities of pure components and their mixtures at 30°C. UV-visible spectra for all the binary mixtures were recorded and showed a characteristic absorption maximum. The results are analyzed in terms of interactions arising due to electrondonor-acceptor (EDA) or charge transfer (CT) complexation.
|
关键字:
|
Molar excess volume ;excess viscosity ;interaction parameter, excess Gibbs energy change for viscous flow, charge transfer complexes and charge transfer bands
|
|
|
|
|
|
所属期刊
|
|
|
ISSN: 0095-9782
|
来自:Springer Nature
|
|