[期刊论文]


Excess volumes and viscosities of mixtures of nitrobenzene and certain aromatic bases

作   者:
K. Govindan;G. Ravichandran;

出版年:1996

页     码:75 - 82
出版社:Springer Nature


摘   要:

Excess molar volumes V E , excess viscosities η E , excess Gibbs energy changes for viscous flow ΔG‡ E and interaction parameters d for binary mixtures of nitrobenzene with aniline, N-methylaniline and m-chloroaniline at selected compositions were determined from the measured values of densities and viscosities of pure components and their mixtures at 30°C. UV-visible spectra for all the binary mixtures were recorded and showed a characteristic absorption maximum. The results are analyzed in terms of interactions arising due to electrondonor-acceptor (EDA) or charge transfer (CT) complexation.



关键字:

Molar excess volume ;excess viscosity ;interaction parameter, excess Gibbs energy change for viscous flow, charge transfer complexes and charge transfer bands


所属期刊
Journal of Solution Chemistry
ISSN: 0095-9782
来自:Springer Nature